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Exercises on acids, salts and bases

 

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Worked Exercises

Identify the following chemical species as Bronsted-Lowry acid or base:

a. \(\ce{HF}\)

b. \(\ce{PO}_{4}^{3-}\)

Answers

a. A Bronsted-Lowry acid as it contains hydrogen that can be donated as \(\ce{H}^{+}\).

b. The phosphate ion does not contain hydrogen. However, oxygen atoms present in the phosphate ion have lone pairs of electrons which can be shared with a proton/protons or a hydrogen ion/ions. Therefore, the phosphate ion is a Bronsted-Lowry base.

Write the formula for:

  1. the conjugate base of \(\ce{H}_{3}\ce{PO}_{4}\) ,

  2. the conjugate acid of \(\ce{NO}_{3}^{-}\).

Answers

After donating one hydrogen ion, \(\ce{H}_{3}\ce{PO}_{4}\) becomes \(\ce{H}_{2}\ce{PO}_{4}^{-}\). Therefore, the conjugate base of \(\ce{H}_{3}\ce{PO}_{4}\) is the \(\ce{H}_{2}\ce{PO}_{4}^{-}\) ion.

As a base \(\ce{NO}_{3}^{-}\) accepts a proton from an acid and becomes \(\ce{HNO}_{3}\). Therefore, the conjugate acid of \(\ce{NO}_{3}^{-}\) is the \(\ce{HNO}_{3}\).

1. \[ \ce{H}_{3}\ce{PO}_{4}\rightarrow\ce{H}^{+}+\ce{H}_{2}\ce{PO}_{4}^{-} \]

2. \[ \ce{NO}_{3}^{-}+\ce{H}^{+}\rightarrow\ce{HNO}_{3} \]

Exercises

Identify the following chemical species as a Bronsted-Lowry acid or base:

\(\ce{HClO}_{4}\)

Acid

\(\ce{HCOOH}\)

Acid

\(\ce{CN}^{-}\)

Base

\(\ce{SO}_{3}^{2-}\)

Base

\(\ce{H}_{2}\ce{S}\)

Acid

Write the chemical formulas for each of the following:

The conjugate acid of \(\ce{HS}^{-}\)

\(\ce{H}_{2}\ce{S}\)

The conjugate base of \(\ce{NH}_{4}^{+}\)

\(\ce{NH}_{3}\)

The conjugate acid of \(\ce{PO}_{4}^{3-}\)

\(\ce{HPO}_{4}^{2-}\)

The conjugate acid of \(\ce{HC}_{2}\ce{O}_{4}^{-}\)

\(\ce{H}_{2}\ce{C}_{2}\ce{O}_{4}\)

The conjugate base of \(\ce{H}_{2}\ce{CO}_{3}\)

\(\ce{HCO}_{3}^{-}\)

Classify the following acids as monoprotic, diprotic or triprotic:

\(\ce{H}_{2}\ce{SO}_{4}\)

Diprotic

\(\ce{HClO}_{4}\)

Monoprotic

\(\ce{H}_{3}\ce{PO}_{4}\)

Triprotic